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Appendix A

Description of methods for corrosion testing

A complete reference of the corrosion testing methods referenced throughout this guide, including cycle steps, electrolyte solution, and pH range for each standard.

Standard Cycle Note Solution pH Cycle steps
ASTM B117 General: fine mist (atomized with compressed air) sprayed indirectly onto specimens 5 ± 1% NaCl 6.5–7.2 100% Fog @ 35 ± 2°C
ASTM G85
ASTM G85 A1 Acetic acid salt spray 5 ± 1% NaCl + acetic acid to required pH 3.1–3.3 100% Fog @ 35 ± 2°C
ASTM G85 A2 Cyclic acidified salt fog 5 ± 1% NaCl 2.8–3.0 0.75h Fog @ 49 ± 2°C
2h Dry air purge
3.25h Humidity
ASTM G85 A3 Acidified synthetic seawater Synthetic sea salt 2.8–3.0 0.5h Fog @ 24 to 35 or 49 ± 2°C
1.5h Humidity
ASTM G85 A5 Dilute electrolyte cyclic fog/dry 0.35% (NH₄)₂SO₄ + 0.05% NaCl 5.0–5.4 1h Fog
1h Dry @ 35 ± 1.5°C
ASTM D2247 Humidity 100% Relative Humidity @ 38 ± 2°C
ASTM E1925
ASTM E1925 7.12 Humidity resistance for rigid wall 20h >97% Relative Humidity
4h 100% Relative Humidity
ASTM E1925 Marine atmosphere for rigid wall 10% 6.5–7.2 96h Fog @ 35 ± 2°C
MIL-STD-810G 509.5 Salt fog 5 ± 1% NaCl 6.5–7.2 24h Fog @ 35 ± 2°C
24h Ambient dry
ISO 9227
ISO 9227 NSS Neutral salt spray 5 ± 1% NaCl 6.5–7.2 100% Fog @ 35 ± 2°C
ISO 9227 AASS Acetic acid salt spray 5 ± 1% NaCl 3.1–3.3 100% Fog @ 35 ± 2°C
ISO 9227 CASS Copper-accelerated acetic acid salt spray. For the quality control of inorganic coating systems. 5 ± 1% NaCl + 0.26 g/l CuCl₂·2H₂O 3.1–3.3 100% Fog @ 50 ± 2°C
ASTM D1735 Testing water resistance of coatings using water fog apparatus Water conforming to Type IV or better of Specification D1193 100% Relative Humidity @ 38 ± 2°C
ASTM D5894 Cyclic salt fog/UV exposure of painted metal 0.35% (NH₄)₂SO₄ + 0.05% NaCl 5.0–5.4 1 week — UV (ASTM G154)
1 week — ASTM G85 A5 with modified solution
ISO 11997 — Paints and varnishes: determination of resistance to cyclic corrosion conditions
ISO 11997 Cycle A Wet (salt fog) / dry / humid 5 ± 1% NaCl 6.0–7.0 2h salt fog @ 35 ± 2°C
4h 60 ± 2°C @ 20–30% RH
2h 50 ± 2°C @ >95% RH
ISO 11997 Cycle B Wet (salt fog) / dry / humid 5 ± 1% NaCl 6.0–7.0 24h salt fog @ 35 ± 2°C
8h 40 ± 2°C @ 100% RH
16h 23 ± 2°C @ 50 ± 20% RH
(× 4 repeats)
48h 23 ± 2°C @ 50 ± 20% RH
ISO 11997 Cycle C Wet (salt fog) / dry / humid Sodium chloride (0.31 ± 0.01) g/l + ammonium sulfate (4.1 ± 0.01) g/l 6.0–7.0 210 min salt fog @ 30 ± 2°C
210 min dry @ 40 ± 2°C
1470 min dry @ 40 ± 2°C @ 75 ± 15% RH
102 min dry @ 30 ± 2°C
210 min salt fog @ 30 ± 2°C
378 min dry @ 30 ± 2°C @ 95–100% RH
180 min dry @ 35 ± 2°C
120 min dry @ 25 ± 2°C
ISO 11997 Cycle D Wet (salt fog) / dry / humid 5 ± 1% NaCl 6.0–7.0 0.5h salt fog @ 30 ± 2°C
1.5h 30 ± 2°C @ 95 ± 3% RH
2h dry @ 50 ± 2°C
2h dry @ 30 ± 2°C
SAE J2334 Laboratory cyclic corrosion test 0.075% NaHCO₃ + 0.5% NaCl + 0.1% CaCl₂ 6h @ 50 ± 2°C @ 100% RH
15 min salt application at ambient
7h 45min @ 60°C @ 50% RH
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